In Situ ATR-FTIR Investigation of the Effects of H2O and D2O Adsorption on the TiO2 Surface
نویسندگان
چکیده
منابع مشابه
In situ ATR-FTIR study of H2O and D2O adsorption on TiO2 under UV irradiation.
The adsorption of water and deuterium oxide on TiO2 surfaces was investigated in the dark as well as under UV(A) irradiation using in situ ATR-FTIR spectroscopy under oxygen and oxygen free conditions. Adsorption of H2O-D2O mixtures revealed an isotopic exchange reaction occurring onto the surface of TiO2 in the dark. Under UV(A) irradiation, the amount of both OH and OD groups was found to be ...
متن کاملPhotocatalytic Removal of NOx Gas from Air by TiO2/Polymer Composite Nanofibers
Nitrogen oxides (NOx) released in atmosphere by fuels combustion lead to photochemical smog and acidic rains and have negative effects on human`s nervous system. In this research nanocomposite membranes of Poly Vinylidene Fluoride (PVDF)/ Poly Dimethylsiloxane (PDMS) and Titanium Dioxide nanoparticles (TiO2) with different weight percentage of TiO2 (0.5 and 1) for adsorption of NOx were prepare...
متن کاملAn in Situ ATR-FTIR Investigation of Sulfate Bonding Mechanisms on Goethite.
The mechanism of sulfate adsorption on goethite was investigated in situ using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. Sulfate adsorption was investigated at ionic strengths between 0.005 and 0.1 M, reactant concentrations between 5 and 500 µM, and pH values between 3.5 and 9.0. It was determined that sulfate forms both outer-sphere and inner-sphere surf...
متن کاملAdsorption and Photocatalytic Properties of Surface-Modified TiO2 nanoparticles for Methyl Orange Removal from Aqueous Solutions
Titanium dioxide nanoparticles surface-modified by 5-sulfosalicylic acid 5-SA-TiO2 were prepared in ethanol by the chemisorption process. The effects of surface improvement on the photocatalytic degradation and adsorption of methyl orange MO were studied in a batch system by considering the various parameters, such as contact time, adsorbent dosage, pH, initial dye concentration and temperature...
متن کاملPhosphate adsorption onto hematite: an in situ ATR-FTIR investigation of the effects of pH and loading level on the mode of phosphate surface complexation.
Phosphate adsorption on hematite was characterized as a function of pH (3.5-8.9) and phosphate concentration (5-500 microM) by in situ ATR-FTIR spectroscopy. Under most conditions a mixture of different (inner-sphere) phosphate complexes existed at the hematite surface, with the relative importance of these complexes varying with pH and surface coverage. Experiments using D(2)O and H(2)O indica...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2017